E1 - Gabrielle, Jacob Fortune-Lloyd, Grace Neutral

Aired: October 13, 2021

The contestants are challenged to paint singer Gabrielle, actor Jacob Fortune-Lloyd, and television presenter Grace Neutral. Joan Bakewell and Stephen Mangan present.

E2 - Gyles Brandreth, Karen Gibson, Sophie Cookson

Aired: October 20, 2021

The contestants are challenged to paint actor and presenter Gyles Brandreth, conductor Karen Gibson, and actress Sophie Cookson. Joan Bakewell and Stephen Mangan present.

E3 - Alexa Chung, Nish Kumar, Philip Glenister

Aired: October 27, 2021

The contestants are challenged to paint author Alexa Chung, comedian Nish Kumar, and actor Philip Glenister. Joan Bakewell and Stephen Mangan present.

E4 - Celeste, Lydia West, Alastair Campbell

Aired: November 03, 2021

The contestants are challenged to paint singer-songwriter Celeste, actress Lydia West, and journalist Alastair Campbell. Joan Bakewell and Stephen Mangan present.

E5 - Kelly Macdonald, Hugh Skinner, Polly Walker

Aired: November 10, 2021

The contestants are challenged to paint actress Kelly Macdonald, actor Hugh Skinner, and actress Polly Walker. Joan Bakewell and Stephen Mangan present.

E6 - David Olusoga, Maggie Aderin-Pocock, Sergei Polunin

Aired: November 17, 2021

The contestants are challenged to paint historian David Olusoga, scientist Maggie Aderin-Pocock, and ballet dancer Sergei Polunin. Joan Bakewell and Stephen Mangan present.

E7 - Chris Packham, Arlene Phillips, Ali Jawad

Aired: November 24, 2021

The contestants are challenged to paint naturalist Chris Packham, choreographer Arlene Phillips, and powerlifter Ali Jawad. Joan Bakewell and Stephen Mangan present.

E8 - Ian Hislop, Emma Dabiri, Daniel Mays

Aired: December 01, 2021

The contestants are challenged to paint journalist Ian Hislop, author Emma Dabiri, and actor Daniel Mays. Joan Bakewell and Stephen Mangan present.

E9 - Semi-Final: Nick Mason

Aired: December 08, 2021

The contestants are challenged to paint Pink Floyd drummer Nick Mason. Joan Bakewell and Stephen Mangan present.

E10 - Final: Barry Humphries

Aired: December 15, 2021

In the final, the three remaining artists paint the Australian actor Barry Humphries. The winner is revealed.

E11 - Nicola Benedetti

Aired: December 22, 2021

The winning artist creates a commissioned portrait of Violinist Nicola Benedetti.